where do I start?
if you have 135 points, then there is no need to get a job offer before apply for PR. You may be limited in who will give a job offer to someone without either PR or a work permit and then once you are over there, no matter how bad the company turns out to be you will be stuck working for them for 3 months.
If you have PR first I think you will find it easier and get a better job offer. (usual disclaimer, this is my personal opinion)
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